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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Solid-liquid equilibrium in ternary mixtures of ethyl laurate, ethyl palmitate and ethyl myristate

Texto completo
Autor(es):
Robustillo, Maria Dolores [1] ; Barbosa, Deise Fernanda [1] ; de Almeida Meirelles, Antonio Jose [2] ; Pessoa Filho, Pedro de Alcantara [1]
Número total de Autores: 4
Afiliação do(s) autor(es):
[1] Univ Sao Paulo, Dept Chem Engn, Sch Engn, BR-05424970 Sao Paulo - Brazil
[2] Univ Estadual Campinas, Sch Food Engn FEA, Dept Food Engn DEA, Campinas, SP - Brazil
Número total de Afiliações: 2
Tipo de documento: Artigo Científico
Fonte: Fluid Phase Equilibria; v. 361, p. 188-199, JAN 15 2014.
Citações Web of Science: 7
Resumo

An experimental study into the solid-liquid equilibrium of ternary mixtures of ethyl laurate, ethyl palmitate and ethyl myristate, commonly present in biodiesel, is presented. Experimental results reveal the polymorphism of ethyl myristate and show the existence of a peritectic-type reaction in binary systems containing such compound, as well as in the ternary system. A probable metatectic reaction was also found for the binary system ethyl laurate and ethyl myristate. The experimental results were modeled considering an approach recently developed for systems with immiscible solid phases and peritectic reactions. (C) 2013 Elsevier B.V. All rights reserved. (AU)

Processo FAPESP: 10/18355-1 - Estudo do equilíbrio sólido-líquido de misturas de ésteres etílicos
Beneficiário:Maria Dolores Robustillo Fuentes
Linha de fomento: Bolsas no Brasil - Pós-Doutorado
Processo FAPESP: 08/56258-8 - Phase equilibrium and purification processes in the production of biofuels and biocompounds
Beneficiário:Antonio José de Almeida Meirelles
Linha de fomento: Auxílio à Pesquisa - Programa BIOEN - Temático