Research and development of nanostructured materials for electronic and surface physics applications

• Grant number: 12/10127-5
• Support Opportunities: Research Projects - Thematic Grants
• Start date: July 01, 2013
• End date: March 31, 2019
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Fernando Alvarez
• Grantee: Fernando Alvarez
• Host Institution: Instituto de Física Gleb Wataghin (IFGW). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• City of the host institution: Campinas
• Principal investigators: Antonio Ricardo Zanatta ; Francisco das Chagas Marques ; Maria Cristina dos Santos
• Associated researchers: Luiz Fernando Zagonel ; Roosevelt Droppa Junior
• Associated research grant(s): 14/50718-8 - Ultrathin semiconductors deposited by Atomic Layer Deposition (ALD) for solar cell application, AP.R
• Associated scholarship(s): 19/00757-0 - Study and control of the crystalline orientations in MoS2/TiO2 and MoS2/TiO2:H heterojunctions and their effects on its physicochemical properties, BP.PD; 13/26385-6 - Development and study of nanoparticles that generates multiple excitons and plasmonic effects applied for solar cells, BP.PD

Abstract

The aim of the project is the experimental and theoretical study of the fundamental electronic, optical, structural, mechanical, and surface physics properties of novel micro and/or nanostructured materials, for electronic applications as well as promotes their use in technological applications. The materials will be obtained by Dual Ion Beam Assisted Deposition, Chemical Vapor Deposition, Sputtering, Arc Discharge, Laser Evaporation, and Pulsed Plasma Deposition. These goals are intimately linked to the scientific tradition of our research group and with the current graduate student programs at the Instituto de Física "Gleb Wataghin" and the Instituto de Física da Universidade de São Paulo (São Paulo and São Carlos) as well with the Laboratório Nacional de Luz Sincrotron (LNLS). The incorporation of the Physics Department of the young ABC University to this effort will help to increase the capacity in research and development of this new institution and contribute to the rational use of the scientific equipment. The formation of students at the three levels, i.e., scientific training for under-graduate students, Master and PhD programs, as well as professional pos-doc is of fundamental importance to this proposal. To reach these goals, we shall take advantage of our past experience and the existence of modern experimental facilities such as photoemission electron spectroscopy (XPS, UPS), X-ray diffraction, visible and infra-red optical absorption, nano-hardness, electron microscopy (HRTEM, TEM, SEM), Atomic force microscopy (AFM) and Raman. The project also considers the upgrading and renewing some experimental facilities that have been using continuously since fifteen years ago. The theoretical studies (intimately bonded to our experimental activities) are giving us a unique possibility to have a broad understanding of the studied subjects. We shall continue the studies on carbon nanotubes, hard carbon films, composites, and alloys based in Ti, C, Al, N and rare-earth doped semiconductors. We shall focus the studies on their structural, electronic, optical, and mechanical properties. A theoretical effort to understand the structural properties will be done based on modern quantum chemical techniques and compared with the experimental results. Experimental conditions leading to the improvement our capacity to study the properties of the studied materials will be pursued. Finally, an interaction with the local industry will be taking in account within the frame of the project with the purpose of technological transference of the advances. (AU)

Scientific publications

(43)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

HOYE, ROBERT L. Z.; SCHULZ, PHILIP; SCHELHAS, LAURA T.; HOLDER, AARON M.; STONE, KEVIN H.; PERKINS, JOHN D.; VIGIL-FOWLER, DEREK; SIOL, SEBASTIAN; SCANLON, DAVID O.; ZAKUTAYEV, ANDRIY; et al. Perovskite-Inspired Photovoltaic Materials: Toward Best Practices in Materials Characterization and Calculations. Chemistry of Materials, v. 29, n. 5, p. 1964-1988, MAR 14 2017. (12/10127-5, 14/50718-8)

JIMENEZ, M. J. M.; ANTUNES, V.; CUCATTI, S.; RIUL, JR., A.; ZAGONEL, L. F.; FIGUEROA, C. A.; WISNIVESKY, D.; ALVAREZ, F.. Physical and micro-nano-structure properties of chromium nitride coating deposited by RF sputtering using dynamic glancing angle deposition. SURFACE & COATINGS TECHNOLOGY, v. 372, p. 268-277, AUG 25 2019. (12/10127-5)

COUTINHO, NATALIA F.; CUCATTI, SILVIA; MERLO, RAFAEL B.; SILVA FILHO, JOSE MARIA C.; BORRERO VILLEGAS, NELSON F.; ALVAREZ, FERNANDO; NOGUEIRA, ANA F.; MARQUES, FRANCISCO C.. The Thermomechanical Properties of Thermally Evaporated Bismuth Triiodide Thin Films. SCIENTIFIC REPORTS, v. 9, AUG 13 2019. (12/10127-5, 17/11986-5)

JIMENEZ, M. J. M.; ANTUNES, V. G.; ZAGONEL, L. F.; FIGUEROA, C. A.; WISNIVESKY, D.; ALVAREZ, F.. Effect of the period of the substrate oscillation in the dynamic glancing angle deposition technique: A columnar periodic nanostructure formation. SURFACE & COATINGS TECHNOLOGY, v. 383, FEB 15 2020. (12/10127-5)

CEMIN, FELIPE; TSUKAMOTO, MAKOTO; KERAUDY, JULIEN; ANTUNES, VINICIUS GABRIEL; HELMERSSON, ULF; ALVAREZ, FERNANDO; MINEA, TIBERIU; LUNDIN, DANIEL. Low-energy ion irradiation in HiPIMS to enable anataseTiO(2) selective growth. JOURNAL OF PHYSICS D-APPLIED PHYSICS, v. 51, n. 23, JUN 13 2018. (12/10127-5)

ZANATTA, A. R.. Whitish light-emitting ZnO micro-flakes: their production and optical properties. OPTICAL MATERIALS EXPRESS, v. 8, n. 2, p. 270-275, FEB 1 2018. (12/10127-5)

CUCATTI, S.; OCHOA, E. A.; MORALES, M.; DROPPA, JR., R.; GARCIA, J.; PINTO, H. C.; ZAGONEL, L. F.; WISNIVESKY, D.; FIGUEROA, C. A.; ALVAREZ, F.. Effect of bombarding steel with Xe+ ions on the surface nanostructure and on pulsed plasma nitriding process. Materials Chemistry and Physics, v. 149, p. 261-269, JAN 15 2015. (12/10127-5)

ERMAKOV, VIKTOR A.; CLEMENTE DA SILVA FILHO, JOSE MARIA; BONATO, LUIZ GUSTAVO; VARDHAN MOGILI, NAGA VISHNU; MONTORO, FABIANO EMMANUEL; IIKAWA, FERNANDO; NOGUEIRA, ANA FLAVIA; CESAR, CARLOS LENZ; JIMENEZ-VILLAR, ERNESTO; MARQUES, FRANCISCO CHAGAS. Three-Dimensional Superlattice of PbS Quantum Dots in Flakes. ACS OMEGA, v. 3, n. 2, p. 2027-2032, FEB 2018. (05/51689-2, 13/26385-6, 11/51959-0, 12/10127-5, 17/05854-9)

ANTUNES, V. G.; FIGUEROA, C. A.; ALVAREZ, F.. A comprehensive study of the TiN/Si interface by X-ray photoelectron spectroscopy. Applied Surface Science, v. 448, p. 502-509, AUG 1 2018. (12/10127-5)

CLEMENTE DA SILVA FILHO, JOSE MARIA; MARQUES, FRANCISCO CHAGAS. Structural and optical temperature-dependent properties of PbS thin films deposited by radio frequency sputtering. MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, v. 91, p. 188-193, MAR 2019. (12/10127-5)

CUCATTI, S.; DROPPA, JR., R.; FIGUEROA, C. A.; KLAUS, M.; GENZEL, CH.; ALVAREZ, F.. Residual stress in nano-structured stainless steel (AISI 316L) prompted by Xe+ ion bombardment at different impinging angles. Journal of Applied Physics, v. 120, n. 14, OCT 14 2016. (12/10127-5)

MORALES, M.; MERLO, R. B.; DROPPA, JR., R.; ALVAREZ, F.. Self-organized 2D Ni particles deposited on titanium oxynitride-coated Si sculpted by a low energy ion beam. JOURNAL OF PHYSICS D-APPLIED PHYSICS, v. 47, n. 19, MAY 14 2014. (12/10127-5)

VILLEGAS BORRERO, NELSON FABIAN; CLEMENTE DA SILVA FILHO, JOSE MARIA; ERMAKOV, VIKTOR A.; MARQUES, FRANCISCO CHAGAS. Silver nanoparticles produced by laser ablation for a study on the effect of SERS with low laser power on N719 dye and Rhodamine-B. MRS ADVANCES, v. 4, n. 11-12, p. 723-731, 2019. (12/10127-5, 13/26385-6)

ERMAKOV, VICTOR A.; JIMENEZ-VILLAR, ERNESTO; CLEMENTE DA SILVA FILHO, JOSE MARIA; YASSITEPE, EMRE; VARDHAN MOGILI, NAGA VISHNU; IIKAWA, FERNANDO; DE SA, GILBERTO FERNANDES; CESAR, CARLOS LENZ; MARQUEST, FRANCISCO CHAGAS. Size Control of Silver-Core/Silica-Shell Nanoparticles Fabricated by Laser-Ablation-Assisted Chemical Reduction. Langmuir, v. 33, n. 9, p. 2257-2262, MAR 7 2017. (05/51689-2, 13/26385-6, 11/51959-0, 12/10127-5)

CLEMENTE DA SILVA FILHO, JOSE MARIA; ERMAKOV, VIKTOR A.; MARQUES, FRANCISCO CHAGAS. Perovskite Thin Film Synthesised from Sputtered Lead Sulphide. SCIENTIFIC REPORTS, v. 8, JAN 24 2018. (12/10127-5, 13/26385-6)

SALES DE MELLO, S. R.; MAIA DA COSTA, M. E. H.; MENEZES, C. M.; BOEIRA, C. D.; FREIRE, JR., F. L.; ALVAREZ, F.; FIGUEROA, C. A.. On the phonon dissipation contribution to nanoscale friction by direct contact. SCIENTIFIC REPORTS, v. 7, JUN 12 2017. (12/10127-5)

CLEMENTE DA SILVA FILHO, JOSE MARIA; VILLEGAS BORRERO, NELSON FABIAN; VIANA, GUSTAVO ALEXANDRE; MERLO, RAFAEL BORGES; MARQUES, FRANCISCO CHAGAS. Lead Iodide Thin Films via rf Sputtering. Crystal Growth & Design, v. 20, n. 3, p. 1531-1537, MAR 2020. (12/10127-5)

LITORIA, ADITYA K.; JOSHI, MANOJ D.; ANTUNES, V.; SINGH, DIGVIJAY; FIGUEROA, CARLOS A.; ALVAREZ, F.; HOSMANI, SANTOSH S.. The response of boronized 34CrAlMo5-10 (EN41B) steel to nanoindentation, oxidation, and wear. PHILOSOPHICAL MAGAZINE, v. 101, n. 7, p. 777-818, APR 3 2021. (12/10127-5, 18/24461-0, 19/00757-0)

CLEMENTE DA SILVA FILHO, JOSE MARIA; LANDERS, RICHARD; MARQUES, FRANCISCO CHAGAS. Lead Iodide and Perovskite Films Obtained by Iodination of PbS Thin Films. Journal of Inorganic and Organometallic Polymers and Materials, v. 29, n. 6, p. 2161-2167, NOV 2019. (12/10127-5)

MARQUES, FRANCISCO CHAGAS; SOARES CORTES, ANDRESA DEOCLIDIA; MEI, PAULO ROBERTO. Solar Cells Fabricated in Upgraded Metallurgical Silicon, Obtained Through Vacuum Degassing and Czochralski Growth. SILICON, v. 11, n. 1, p. 77-83, FEB 2019. (12/10127-5)

COUTINHO, NATALIA F.; CUCATTI, SILVIA; MERLO, RAFAEL B.; ANTUNES, VINICIUS G.; ALVAREZ, FERNANDO; MARQUES, FRANCISCO C.. Stress, Hardness and Elastic Modulus of Bismuth Triiodide (BiI3). MRS ADVANCES, v. 3, n. 64, p. 3925-3931, 2018. (12/10127-5)

HOYE, ROBERT L. Z.; SCHULZ, PHILIP; SCHELHAS, LAURA T.; HOLDER, AARON M.; STONE, KEVIN H.; PERKINS, JOHN D.; VIGIL-FOWLER, DEREK; SIOL, SEBASTIAN; SCANLON, DAVID O.; ZAKUTAYEV, ANDRIY; et al. Perovskite-Inspired Photovoltaic Materials: Toward Best Practices in Materials Characterization and Calculations. CHEMISTRY OF MATERIALS, v. 29, n. 5, p. 25-pg., 2017-03-14. (14/50718-8, 12/10127-5)

ZAGONEL, L. F.; TIZEI, L. H. G.; VITIELLO, G. Z.; JACOPIN, G.; RIGUTTI, L.; TCHERNYCHEVA, M.; JULIEN, F. H.; SONGMUANG, R.; OSTASEVICIUS, T.; DE LA PENA, F.; et al. Nanometer-scale monitoring of quantum-confined Stark effect and emission efficiency droop in multiple GaN/AlN quantum disks in nanowires. Physical Review B, v. 93, n. 20, MAY 6 2016. (12/10127-5, 14/23399-9)

KOCIAK, M.; ZAGONEL, L. F.. yy Cathodoluminescence in the scanning transmission electron microscope. ULTRAMICROSCOPY, v. 176, n. SI, p. 112-131, MAY 2017. (12/10127-5, 14/23399-9)

ZANATTA, A. R.; SCOCA, D.; ALVAREZ, F.. A suitable (wide-range plus linear) temperature sensor based on Tm3+ ions. SCIENTIFIC REPORTS, v. 7, OCT 26 2017. (12/10127-5)

DA SILVA, BRUNO C.; OLIVEIRA, DOUGLAS S.; IIKAWA, FERNANDO; COUTO, JR., ODILON D. D.; BETTINI, JEFFERSON; ZAGONEL, LUIZ F.; COTTA, MONICA A.. Exploring Au Droplet Motion in Nanowire Growth: A Simple Route toward Asymmetric GaP Morphologies. Nano Letters, v. 17, n. 12, p. 7274-7282, DEC 2017. (12/11382-9, 15/16611-4, 16/16365-6, 14/23399-9, 13/02300-1, 12/10127-5)

RAMOS, RAUL; SCOCA, DIEGO; MERLO, RAFAEL BORGES; MARQUES, FRANCISCO CHAGAS; ALVAREZ, FERNANDO; ZAGONEL, LUIZ FERNANDO. Study of nitrogen ion doping of titanium dioxide films. Applied Surface Science, v. 443, p. 619-627, JUN 15 2018. (12/10127-5, 14/23399-9)

COUTINHO, NATALIA F.; MENLO, RAFAEL B.; BORRERO, V, NELSON F.; MARQUES, FRANCISCO C.. Thermal Evaporated Bismuth Triiodide (BiI3) Thin Films for Photovoltaic Applications. MRS ADVANCES, v. 3, n. 55, p. 3233-3236, 2018. (12/10127-5)

SCOCA, DIEGO L. S.; CEMIN, FELIPE; BILMES, SARA A.; FIGUEROA, CARLOS A.; ZANATTA, ANTONIO R.; ALVAREZ, FERNANDO. Role of Rare Earth Elements and Entropy on the Anatase-To-Rutile Phase Transformation of TiO2 Thin Films Deposited by Ion Beam Sputtering. ACS OMEGA, v. 5, n. 43, p. 28027-28036, NOV 3 2020. (12/10127-5, 18/24461-0, 19/18460-4)

ECHEVERRIGARAY, FERNANDO G.; DE MELLO, SARON R. S.; LEIDENS, LEONARDO M.; MAIA DA COSTA, MARCELO E. H.; ALVAREZ, FERNANDO; BURGO, THIAGO A. L.; MICHELS, ALEXANDRE F.; FIGUEROA, CARLOS A.. Towards superlubricity in nanostructured surfaces: the role of van der Waals forces. Physical Chemistry Chemical Physics, v. 20, n. 34, p. 21949-21959, SEP 14 2018. (12/10127-5)

BOGONI JR, NERIO; MENEZES, CAREN M.; COSTI, FERNANDA B.; PEROTTI, BRUNA L.; ECHEVERRIGARAY, FERNANDO G.; PEROTTONI, CLAUDIO A.; ALVAREZ, FERNANDO; FIGUEROA, CARLOS A.. Nanoscopic origin of the dissipative friction forces on a diamond tip sliding on magnetite surfaces. Thin Solid Films, v. 660, p. 258-262, AUG 30 2018. (12/10127-5)

ECHEVERRIGARAY, F. G.; SALES DE MELLO, S. R.; BOEIRA, C. D.; LEIDENS, L. M.; MAIA DA COSTA, M. E. H.; FREIRE, JR., F. L.; ALVAREZ, F.; MICHELS, A. F.; FIGUEROA, C. A.. Nanoindentation unidirectional sliding and lateral force microscopy: Evaluation of experimental techniques to measure friction at the nanoscale. AIP ADVANCES, v. 8, n. 12, DEC 2018. (12/10127-5)

JIMENEZ-VILLAR, ERNESTO; XAVIER, M. C. S.; WETTER, NIKLAUS U.; MESTRE, VALDECI; MARTINS, WELITON S.; BASSO, GABRIEL F.; ERMAKOV, V. A.; MARQUES, F. C.; DE SA, GILBERTO F.. Anomalous transport of light at the phase transition to localization: strong dependence with incident angle. PHOTONICS RESEARCH, v. 6, n. 10, p. 929-942, OCT 1 2018. (12/10127-5, 17/10765-5, 17/05854-9)

CEMIN, F.; BIM, L. T.; LEIDENS, L. M.; MORALES, M.; BAUMVOL, I. J. R.; ALVAREZ, F.; FIGUEROA, C. A.. Identification of the Chemical Bonding Prompting Adhesion of a-C:H Thin Films on Ferrous Alloy Intermediated by a SiCx:H Buffer Layer. ACS APPLIED MATERIALS & INTERFACES, v. 7, n. 29, p. 15909-15917, JUL 29 2015. (12/10127-5)

VALES, S.; BRITO, P.; PINEDA, F. A. G.; OCHOA, E. A.; DROPPA, JR., R.; GARCIA, J.; MORALES, M.; ALVAREZ, F.; PINTO, H.. Influence of substrate pre-treatments by Xe+ ion bombardment and plasma nitriding on the behavior of TiN coatings deposited by plasma reactive sputtering on 100Cr6 steel. Materials Chemistry and Physics, v. 177, p. 156-163, JUL 1 2016. (12/10127-5, 10/11391-2)

FREISLEBEM, MARCIA; MENEZES, CAREN M.; CEMIN, FELIPE; COSTI, FERNANDA B.; FERREIRA, PATRICIA A.; AGUZZOLI, CESAR; BAUMVOL, ISRAEL J. R.; ALVAREZ, FERNANDO; FIGUEROA, CARLOS A.. Influence of the chemical surface structure on the nanoscale friction in plasma nitrided and post-oxidized ferrous alloy. Applied Physics Letters, v. 105, n. 11, SEP 15 2014. (12/10127-5)

MORALES, M.; DROPPA, JR., R.; DE MELLO, S. R. S.; FIGUEROA, C. A.; ZANATTA, A. R.; ALVAREZ, F.. Self-organized nickel nanoparticles on nanostructured silicon substrate intermediated by a titanium oxynitride (TiNxOy) interface. AIP ADVANCES, v. 8, n. 1, JAN 2018. (12/10127-5)

CEMIN, F.; BIM, L. T.; MENEZES, C. M.; MAIA DA COSTA, M. E. H.; BAUMVOL, I. J. R.; ALVAREZ, F.; FIGUEROA, C. A.. The influence of different silicon adhesion interlayers on the tribological behavior of DLC thin films deposited on steel by EC-PECVD. SURFACE & COATINGS TECHNOLOGY, v. 283, p. 115-121, DEC 15 2015. (12/10127-5)

CRESPI, A. E.; LEIDENS, L. M.; AGUZZOLI, C.; ALVAREZ, F.; FIGUEROA, C. A.. Influence of hydrogen etching on the adhesion of coated ferrous alloy by hydrogenated amorphous carbon deposited at low temperature. VACUUM, v. 144, p. 243-246, OCT 2017. (12/10127-5)

LANZA, GUSTAVO; JIMENEZ, MAWIN J. MARTINEZ; ALVAREZ, FERNANDO; PEREZ-TABORDA, JAIME ANDRES; AVILA, ALBA. Valence State Tuning of Gold Nanoparticles in the Dewetting Process: An X-ray Photoelectron Spectroscopy Study. ACS OMEGA, v. N/A, p. 7-pg., 2022-09-15. (12/10127-5, 19/18460-4)

ANTUNES, VINICIUS G.; FIGUEROA, CARLOS A.; ALVAREZ, FERNANDO. Chemisorption Competition between H2O and H-2 for Sites on the Si Surface under Xe+ Ion Bombardment: An XPS Study. Langmuir, v. 38, n. 6, p. 8-pg., 2022-02-15. (12/10127-5, 19/00757-0, 19/18460-4, 18/24461-0)

KOCIAK, M.; ZAGONEL, L. F.. Cathodoluminescence in the scanning transmission electron microscope. ULTRAMICROSCOPY, v. 176, p. 20-pg., 2017-05-01. (14/23399-9, 12/10127-5)

ZAGONEL, L. F.; TIZEI, L. H. G.; VITIELLO, G. Z.; JACOPIN, G.; RIGUTTI, L.; TCHERNYCHEVA, M.; JULIEN, F. H.; SONGMUANG, R.; OSTASEVICIUS, T.; DE LA PENA, F.; et al. Nanometer-scale monitoring of quantum-confined Stark effect and emission efficiency droop in multiple GaN/AlN quantum disks in nanowires. PHYSICAL REVIEW B, v. 93, n. 20, p. 12-pg., 2016-05-06. (14/23399-9, 12/10127-5)

Filed patent(s) as a result of this research project